说走就走！济南至新加坡、越南芽庄航线正式复航

2、说走环境的因素改变也会导致狗狗咳嗽。

走济南加坡e,标准实验条件下2-MF光催化脱氢偶联反应结果。至新正式该领域近5年相关工作（生物质转化）：1.NengchaoLuo,TizianoMontini,JianZhang,PaoloFornasiero,EmilianoFonda,TingtingHou,WeiNie,JianminLu,JunxueLiu,MarcHeggen,LongLin,ChangtongMa,MinWang,FengtaoFan,ShengyeJin,FengWang*.Visible-light-drivencoproductionofdieselprecursorsandhydrogenfromlignocellulose-derivedmethylfurans.Nat.Energy,2019,doi:10.1038/s41560-019-0403-5.2.YehongWang,MiPeng,JianZhang,ZhixinZhang,JinghuaAn,ShuyanDu,HongyuAn,FengtaoFan,XiLiu,PengZhai,DingMa*,FengWang*.Selectiveproductionofphase-separableproductfromamixtureofbiomass-derivedaqueousoxygenates.Nat.Commun.,2018,9,5183.3.YanchengHu‡,ZhitongZhao‡,YantingLiu,GuangyiLi,AiqinWang,YuCong,TaoZhang,FengWang*,NingLi*.Synthesisof1,4-cyclohexanedimethanol,1,4-cyclohexanedicarboxylicacidand1,2-cyclohexanedicarboxylatesfromformaldehyde,crotonaldehydeandacrylate.Angew.Chem.Int.Ed.,2018,57(23),6901-6905.4.HongjiLi,ElenaSubbotina,AnonBunrit,FengWang*,JosephS.M.Samec*.Functionalizedspirolactonesbyphotoinduceddearomatizationofbiarylcompounds.Chem.Sci.,2019,10,3681-3686.5.MinWang,MeijiangLiu,HongjiLi,ZhitongZhao,XiaochenZhang,FengWang*.Dealkylationoflignintophenolviaoxidation–hydrogenationstrategy.ACSCatal.,2018,8(8),6837-6843.6.HuifangLiu,HongjiLi,JianminLu,ShuZeng,MinWang,NengchaoLuo,ShutaoXu,FengWang*.PhotocatalyticcleavageofC–Cbondinligninmodelsundervisiblelightonmesoporousgraphiticcarbonnitridethroughπ-πstackinginteraction.ACSCatal.,2018,8(6),4761-4771.7.MinWang,JipingMa,HuifangLiu,NengchaoLuo,ZhitongZhao,FengWang*.SustainableproductionsoforganicacidsandtheirderivativesfrombiomassviaselectiveoxidativecleavageofC-Cbond.ACSCatal.,2018,8(3),2129-2165.8.MinWang,XiaochenZhang,HongjiLi,JianminLu,MeijiangLiu,FengWang*.Carbonmodificationofnickelcatalystfordepolymerizationofoxidizedlignintoaromatics.ACSCatal.,2018,8(2),1614-1620.9.NengchaoLuo,MinWang,HongjiLi,JianZhang,TingtingHou,HaijunChen,XiaochenZhang,JianminLu,FengWang*.Visible-light-drivenself-hydrogentransferhydrogenolysisofligninmodelsandextractsintophenolicproducts.ACSCatal.,2017,7(7),4571-4580.10.HongjiLi,MinWang,HuifangLiu,NengchaoLuo,JianminLu,ChaofengZhang,FengWang*.NH2OH-mediatedligninconversiontoisoxazoleandnitrile.ACSSustainableChem.Eng.,2018,6(3),3748-3753.11.TingtingHou,NengchaoLuo,HongjiLi,MarcHeggen,JianminLu,YehongWang,FengWang*.YinandYangdualcharactersofCuOxclustersforC–Cbondoxidationdrivenbyvisiblelight.ACSCatal.,2017,7(6),3850–3859.12.ChaofengZhang,HongjiLi,JianminLu,XiaochenZhang,KatherineEMacArthur,MarcHeggen,FengWang*.Promotinglignindepolymerizationandrestrainingthecondensationviaanoxidation-hydrogenationstrategy.ACSCatal.,2017,7(5),3419–3429.13.NengchaoLuo,MinWang,HongjiLi,JianZhang,HuifangLiu,FengWang*.Photocatalyticoxidation-hydrogenolysisofligninβ-O-4modelsviaaduallightwavelengthswitchingstrategy.ACSCatal.,2016,6(11),7716–7721.14.MinWang,JianminLu,XiaochenZhang,LihuaLi,HongjiLi,NengchaoLuo,FengWang*.Two-step,catalyticC–Cbondoxidativecleavageprocessconvertsligninmodelsandextractstoaromaticacids.ACSCatal.,2016,6(9),6086–6090.15.JianminLu,MinWang,XiaochenZhang,AndreasHeyden,FengWang*.β-O-4bondcleavagemechanismforligninmodelcompoundsoverPdcatalystsidentifiedbycombinationoffirst-principlescalculationsandexperiments.ACSCatal.,2016,6(8),5589–5598.16.MinWang,LihuaLi,JianminLu,HongjiLi,XiaochenZhang,HuifangLiu,NengchaoLuo,FengWang*.AcidpromotedC–Cbondoxidativecleavageofβ-O-4andβ-1ligninmodelstoestersoveracoppercatalyst.GreenChem.,2017,19(3),702-706.17.ChaofengZhang,JianminLu,XiaochenZhang,KatherineEMacArthur,MarcHeggen,HongjiLi,FengWang*.Cleavageofligninβ-O-4etherbondviadehydroxylation-hydrogenationstrategyoveraNiMosulfidecatalyst.GreenChem.,2016,18(24),6545-6555.18.ChaofengZhang,FengWang*.Selladummy:Adjacentfunctionalgroupmodificationstrategyforthecatalyticcleavageofligninβ-O-4linkage.Chin.J.Catal.,2017.38(7),1102-1107.文献链接: Visible-light-drivencoproductionofdieselprecursorsandhydrogenfromlignocellulose-derivedmethylfurans本文由luna编译供稿。

图3.在可见光驱动下，越南芽庄2,5-DMF/2-MF经光催化脱氢偶联反应转化为柴油a,2,5-DMF/2-MF转化为柴油的过程中所涉及的代表性化学反应b-d,2,5-DMF作为底物光催化脱氢耦合的结果:(b)标准条件实验，越南芽庄(c)催化剂寿命评估，(d)含氧DFPs和支链DFPs的选择性。立足催化反应研究，航线以低碳烯烃和醇类小分子、生物质和烃类化合物等为原料，制备高值含氧/氮化学品，着重研究酸碱催化和氧化还原催化反应。复航e,Ru-ZnIn2S4的FTk3-χ(k)的RuK边EXAFS信号。

【团队介绍】王峰，说走中国科学院大连化学物理研究所研究员，课题组长、生物能源研究部部长、所长助理。走济南加坡b,对二甲苯与对甲基茴香醚的交叉偶联反应结果。

f,标准实验条件下，至新正式光催化2,5-DMF和2-MF(体积比为1:3)的混合物脱氢偶联反应结果

鹰皇严格把关每一道工序、越南芽庄每一个细节，确保灯饰照明工程的每一件产品都是精品。插图：航线UCNP的上转换发射强度随激发强度的变化(c).用于测量UCNP介导的深部脑组织NIR上转换的体内纤维光度测定示意图(d).在不同距离的980nmNIR激光照射下VTA部位的上转换发射光谱(e).发蓝光的NaYF4:Yb/Tm@SiO2UCNP的示意图(f).UCNP介导的NIR光刺激VTA的小鼠体内实验示意图(g).c-Fos阳性神经细胞的百分比(h,i).在不同刺激条件下，航线腹侧纹状体中的瞬时DA浓度(j).在（h）和（i）所示的五种条件下经颅刺激后15秒内腹侧纹状体中的累积DA释放量(k).发绿光的NaYF4:Yb/Er@SiO2UCNP的示意图(l).在四种不同条件下经颅NIR光照射后海马体的共聚焦荧光图像(m).在（1）所示的四种不同条件下c-Fos的表达Figure3.神经细胞活性的光热调控(a).SP1和SP2的化学结构(b).SPN和SPNbc的合成示意图(c).SPN1，SPN2和AuNR的吸收图谱(d).SPN1bc处理后ND7/23细胞和HeLa细胞的荧光图像(e).SPNbc控制的光热激活神经元中TRPV1离子通道的示意图(f).在808nm激光照射之前和照射2秒之后，SPN1bc或SPN2bc处理后的ND7/23细胞或HeLa细胞的荧光图像(g).Fluo-8的荧光强度随激光照射时间的变化(h).Fluo-8的荧光强度随着激光打开和关闭的变化Figure4.光遗传纳米平台用以实现细胞内Ca2+依赖性基因表达的远程光调控(a).链霉抗生物素蛋白修饰的UCNP与基因编辑的ORAI1Ca2+通道之间的相互作用示意图(b).由NIR光照射引发的体内NFAT依赖性荧光素酶表达的示意图(c).移植表达NFAT-Luc的HeLa细胞（左）、表达LOVSoc和NFAT-Luc（中间和右）的HeLa细胞后经过980nm激光照射（左和右）后BALB/c小鼠的生物发光成像。

就这一点而言，复航具有光学性质的纳米材料已经展现出能够将光转换成各种形式的刺激因素从而调控生物过程或者生物分子活性的潜力。至今，说走浦侃裔教授累计发表高档次文章140多篇，SCIH-index=59。

 欢迎大家到材料人宣传科技成果并对文献进行深入解读，走济南加坡投稿邮箱[email protected]。在这方面，至新正式这些光学纳米材料能够将NIR光转换成UV/可见光、热或自由基，从而实现不同的光调控应用。